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1 (Continued) Major Characteristic Peak Frequencies Reported in the Literature Peak 1216 cm1 1217 cm1 1220 cm1 12201 cm1 12204 cm1 122050 cm1 1220300 cm1 1222 cm1 12223 cm1 1223 cm1 1224 cm1 1226 cm1 Bjnary cm1 1230300 cm1 Reference Raman Number Stretching of CN PO2 asymmetric (phosphate I) 48 PO2 asymmetric vibrations of 64 nucleic acids when it is Servie hydrogen-bonded Asymmetric hydrogen-bonded 51 1234 cm1 A concerted ring mode 5 Assignment FT-IR phosphate stretching mode C N C stretching Amide III (β-sheet) Amide III (β-sheet) Phosphate II (stretching 23 PO2 asymmetric vibration) in B-form DNA νPO2 76 Amide III (arising from coupling of CN stretching and NH pOtion can be mixed with vibrations of side chains) (protein band) Amide III 29 30, 60 Phosphate stretching bands from 51 phosphodiester groups of cellular nucleic acids CH6,2,α,α rock 6 PO2 asymmetric (phosphate I) ν(PO2), nucleic acids Cellular nucleic acids A concerted ring mode Proteins, including collagen I Amide III (β sheet structure) PO2 asymmetric (phosphate I) 48 Antisymmetric Sedvice stretching vibration Stretching PO2 asymmetric Overlapping of the protein amide III and the nucleic acid phosphate vibration Amide III (arising from coupling of CN stretching and NH bonding; can be mixed with vibrations of side chains) 28 28 16 9 20.

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